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You can use the following query to create a collection of Windows 8.1 computers –
select SMS_R_System.ResourceId, SMS_R_System.ResourceType, SMS_R_System.Name, SMS_R_System.SMSUniqueIdentifier, SMS_R_System.ResourceDomainORWorkgroup, SMS_R_System.Client from SMS_R_System where SMS_R_System.OperatingSystemNameandVersion like “Microsoft Windows NT Workstation 6.3%“